期刊
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
卷 380, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2019.111862
关键词
Photocatalysis; Visible light irradiation; MIL-53(Fe)/BiOCl/PS; Mechanism
资金
- National Natural Science Foundation of China [21177061]
- Natural Science Foundation of Jiangsu Province [BK20150968]
- Based Pioneering Enterprise Incubation Project of Jiangsu Province [BC2016003]
The novel semiconductor heterojunction of MIL-53(Fe)/BiOCl composite was first prepared through the solvothermal reaction. The prepared materials were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Brunner-Emmet-Teller (BET) and ultraviolet-visible diffuse reflectance spectroscopy (DRS). MIL-53(Fe)/BiOCl heterojunction is a kind of photoexcited materials and it accelerates the photoreactivity of BiOCI under the visible light irradiation. It was used to remove Rhodamine B (RhB) with the existence of persulfate (PS). The UV-vis spectrophotometer and the TOC detector show that the degradation rate and TOC removal efficiency of RhB (20 mg/L) are 99.5% and 69.4%within 30 min visible-light irradiation, respectively. Due to the proper band gap of material and the presence of electron acceptor, PS, the survival time of active radicals are increased. The active species h(+), center dot SO4- and center dot OH are found to play the important roles during the reaction system. The possible mechanism for the RhB degradation of MIL-53(Fe)/BiOCl/PS is also proposed. Furthermore, the results of the material reusability for the degradation of RhB indicate that the MIL-53(Fe)/BiOCl has a good stability and can be used in the environmental water sample treatment.
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