期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 84, 期 16, 页码 10501-10508出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b01431
关键词
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资金
- Innovation Research Projects of Shanghai University of Engineering Science [201810856017, cs1704006, A1-0601-19-01017]
- Opening Project of Shanghai Key Laboratory of Chemical Biology
- RUDN University Program 5-100
A novel and selective cascade reaction of primary amines and alkynes for the synthesis of the corresponding secondary propargylamines is described. This protocol proceeds with a CuBr2/TBHP system through a process of oxidative deamination of primary amines to imine and alkynylation, featuring a wide scope of substrates with good functional-group tolerance and operational simplicity. Additionally, the use of two different primary amines could also work smoothly using this protocol.
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