期刊
JOURNAL OF MOLECULAR LIQUIDS
卷 286, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.molliq.2019.04.096
关键词
Menthol; Phase diagrams; Liquid-liquid equilibrium; High pressure; PC-SAFT; COSMO-RS
资金
- National Science Centre, Poland [UMO-2016/23/B/ST5/00145]
New data on phase equilibria in binary and ternary mixtures containing (-)-menthol, n-decane, 1-decanol and water are presented and discussed. In particular, experimental liquid-liquid equilibrium phase diagrams in ternary systems {(-)-menthol + (n-decane, or 1-decanol) + water) are reported along with the predictions by means of leading thermodynamic models, namely, perturbed-chain statistical associating fluid theory (PC-SAFT) and conductor-like screening model for real solvents (COSMO-RS). Freezing pressure data for binary systems {()-menthol + (n-decane, or 1-decanol)) are reported and the corresponding high-pressure solid-liquid equilibrium phase diagrams are discussed and analyzed by using the Yang equation. The measured data are referred to ambient-pressure phase diagrams published previously. (C) 2019 Elsevier B.V. All rights reserved.
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