4.6 Article

Tunable microwave absorbing property of LaxFeO3/C by introducing A-site cation deficiency

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SPRINGER
DOI: 10.1007/s10854-019-01715-0

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资金

  1. National Natural Science Foundation of China [51407134, 51801001]
  2. China Postdoctoral Science Foundation [2016M590619, 2016M601878]
  3. Natural Science Foundation of Shandong Province [ZR2019YQ24]
  4. Qingdao Postdoctoral Application Research Project, Provincial Key Research and Development Program of Shaanxi [2019GY-197]
  5. Key Project of Baoji University of Arts and Sciences [ZK2018051]
  6. Baoji Science and Technology Project [16RKX1-29]
  7. Baoji Engineering Technology Research Center for Ultrafast Optics and New Materials [2015CXNL-1-3]
  8. Thousand Talents Plan
  9. World-Class University and Discipline
  10. Taishan Scholar's Advantageous and Distinctive Discipline Program of Shandong Province
  11. World-Class Discipline Program of Shandong Province

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A novel two-dimensional electromagnetic (EM) absorbers which consist of LaFeO3 nanoparticles embedded on hierarchical amorphous carbon nanosheets were fabricated by a simple one-pot method. By inducing A-site cation deficiency in LaFeO3 perovskite, the properties of EM absorption were optimized due to the polarization of dipoles between O vacancy and Fe4+. This research is expectant to provide a new strategy for the improved EM absorption performance by inducing the A-site cation deficiency in perovskite crystal lattices. By the magnetic ferrite nanoparticles doped in the dielectric carbon sheets, we got the best La0.8FeO3-y/C possessing larger absorption bandwidth 5.4 GHz from 12.6 to 18.0 GHz and minimum reflection loss of -20.4 dB while La0.6FeO3-y/C which hit the minimum RL value -25.0 dB at 14.8 GHz with the thickness of 3.75 mm.

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