期刊
JOURNAL OF MAGNETIC RESONANCE
卷 306, 期 -, 页码 69-74出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jmr.2019.07.029
关键词
Long-lived state; Singlet state; Spin isomer; Parahydrogen; Quantum rotor; Hyperpolarization
资金
- EPSRC-UK [EP/P009980, EP/P005187, EP/P030491]
- European Research Council [786707-FunMagResBeacons]
- EPSRC [EP/K00509X/1, EP/P030491/1] Funding Source: UKRI
The field of long-lived states in NMR is reviewed. The relationship of long-lived-state phenomena to those associated with spin isomerism is discussed. A brief overview is given of key developments in the field of long-lived states, including chemical symmetry-switching, the role of magnetic equivalence and magnetic inequivalence, long-lived coherences, hyperpolarized NMR involving long-lived states, quantum-rotor-induced polarization, and parahydrogen-induced hyperpolarization. Current application areas of long-lived states are reviewed, and a peer into the crystal ball reveals future developments in the field. (C) 2019 The Author. Published by Elsevier Inc.
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