期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 844, 期 -, 页码 43-48出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2019.04.075
关键词
Enzymatic biofuel cell; Ethanol; Poly(pyrrole); Poly(methylene green); Alcohol dehydrogenase; Simultaneous electropolymerization
资金
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brasil (CAPES) [001]
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico - CNPq [400712/2014-8]
We prepared robust bioanodes by immobilizing the alcohol dehydrogenase (ADH) enzyme onto a one-pot electropolymerized film consisting of methylene green and pyrrole. The enzymatic film containing immobilized ADH furnished power densities as high as 183 +/- 10 mu W cm(-2); addition of carbon nanotubes (MWCNTs) increased the bioanode power density to 275 +/- 12 mu W cm(-2). The bioanode was very stable, with a mean decay of 36% of its initial power density after 20 weeks of storage. Long-term ethanol electrolysis (12h) followed by HPLC-UV/RID confirmed that the system was highly selective and generated a two-electron product. MWNCT introduction provided five times higher acetaldehyde production. Compared to literature data, results were promising and showed that the system can be used to construct biofuel cells. In addition, the film obtained by simultaneous methylene green and pyrrole electropolymerization afforded interesting results and can be applied in other systems, such as biosensors.
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