期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 794, 期 -, 页码 94-100出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2019.04.203
关键词
Green-emitting phosphor in glass; BaO-B2O3-ZnO-SiO2 (BBZS) glass frits; White LEDs; Laser diode based lighting; Solid state lighting system
资金
- Industrial Strategic Technology Development Program - Ministry of Trade, Industry and Energy, KOREA [10047778]
- Korea Evaluation Institute of Industrial Technology (KEIT) [10047778] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Green-emitting phosphor-in-glass (PiG) materials with a high luminescence efficiency and high color rendering index were developed by co-firing commercial beta-SiAlON: Eu2+ phosphor powder and BaO-B2O3-ZnO-SiO2 (BBZS) glass frits possessing a low glass transition temperature (T-g = 560 degrees C). In agreement with the photoluminescence spectral profiles of powder materials, beta-SiAlON: Eu2+ PiG materials showed a broad excitation band from 220 to 500 nm and a narrow emission band at 530 nm under excitation at 450 nm. The beta-SiAlON: Eu2+-based PiG exhibited excellent heat resistance, with its relative emission intensity at 200 degrees C being 83% that at 30 degrees C. On varying the beta-SiAlON: Eu2+ phosphor content in the PiG-based light emitting diodes (LEDs), the highest luminous efficacy was obtained for the 10 wt% beta-SiAlON: Eu2+ phosphor-doped PiG sample, and the internal quantum efficiency of this sample under excitation at 450 nm was 56%. By combining the PiG materials prepared in this study with a blue chip-on-board (incident power = 100mA), the 10 wt% beta-SiAlON: Eu2+-based PiG chip module showed a luminous efficacy of 80 lm/Wrad. The PiG-based LED maintained its high luminous efficacy when incident power on the blue chip-on-board increased up to 4W (220 lm/Wrad). Under blue laser excitation (incident power = 1500 mA), the beta-SiAlON: Eu2+-based PiG materials showed a linear relationship between luminous flux and incident laser power. With increasing incident laser power, the luminous flux effectively increased, and the 10 wt% beta-SiAlON: Eu2+-based PiG sample showed a luminous efficacy of 300 lm at an incident laser power of 1500 mA. (c) 2019 Elsevier B.V. All rights reserved.
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