期刊
INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION
卷 24, 期 6, 页码 533-547出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/1023666X.2019.1622719
关键词
Corn oil; isosorbide; polyetheramide; urethane; corrosion
资金
- King Saud University, Deanship of Scientific Research, College of Science Research Center
Poly(urethane-ether-amide) (PUIEtA) nanocomposite coatings on mild steel were prepared by using corn oil, isosorbide and isophorone diisocynate and fumed silica. The syntheses steps were confirmed by FTIR, H-1 NMR and C-13 NMR spectroscopy techniques. The morphology of PUIEtA nanocomposite coating was studied by SEM-EDX, that confirmed the presence of nanosilica and thermal behavior was studied by DSC/TGA analysis. The anticorrosion performance of PUIEtA coating systems on mild steel, exposed to 3.5wt% NaCl solution, was evaluated using electrochemical impedance spectroscopy. Scratch hardness, pencil hardness, adhesion, and bending test were performed in order to investigate the performance of nanocomposite coating on mild steel substrate. It was found that PUIEtA-fumed silica nanocomposite coating could provide much better protection than PUIEtA. PUIEtA-3 nanocomposite coating can be safely used up to 200 degrees C.
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