期刊
INORGANIC CHEMISTRY
卷 58, 期 14, 页码 8922-8926出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b01207
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资金
- U.S. Department of Energy, Office of Science, Basic Energy Sciences, Division of Materials Sciences and Engineering [KC020105-FWP12152]
- U.S. Department of Energy [DE-AC05-76RL01830]
- Natural Science Foundation of China [21601102, 21606007]
- Natural Science Foundation of Shandong Province [ZR2016BQ34]
- Scientific and Technical Development Project of Qingdao [18-2-2-32-jch]
- International Postdoctoral Exchange Fellowship Program [20170035]
Herein we report the first example of a metal-organic framework (MOF) in which the location of Li+ ions trapped in the porous confinement can be unambiguously defined by single-crystal X-ray diffraction. Furthermore, the Li+-doped MOF shows significant enhancement in gas uptake as well as selective adsorption of CO2 over CH4.
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