期刊
INORGANIC CHEMISTRY
卷 58, 期 16, 页码 10912-10919出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b01315
关键词
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资金
- American University of Beirut Research Board
- Lebanese National Council for Scientific Research Award [A103496, A103487]
- K. Shair Central Research Science Laboratory
Current research on metal-organic framework (MOF) luminescent sensing probes focuses on the design of three-dimensional bulk-sized MOFs that in return limits their up-close interactions with targeted guest molecules. In this work, we report a two-dimensional (2D) copper-based metal organic framework, namely, AUBM-6, synthesized via solvo-thermal method from isonicotinic acid linker and copper(II) ion. The resulting 2D-layered MOF crystals were highly fluorescent in their exfoliated form and, therefore, explored for detecting several solvents, where a ratiometric selectivity was shown toward acetone. Metal ion sensing was also performed, by which fluorescent detection was observed to have the highest turn-off quenching efficiency toward Pd2+.
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