期刊
INORGANIC CHEMISTRY
卷 58, 期 12, 页码 7705-7714出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b03487
关键词
-
资金
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- HydroGEN Advanced Water Splitting Materials Consortium, as part of the Energy Materials Network under the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Fuel Cell Technologies Office [DE-EE0008087, DE-EE0008089]
- Brazilian Centro Nacional de Pesquisa (CNPq) [233746/2014-5]
- Center for Advanced Non-Ferrous Structural Alloys (CANFSA), a National Science Foundation Industry/University Cooperative Research Center (I/UCRC), at the Colorado School of Mines (CSM), in Golden, CO, USA [1624836]
- CAPES (Coordination for the Improvement of Higher Education Personnel) [BEX: 13452-13-4]
- Science Without Borders Program - Brazilian government
Ruddlesden-Popper (layered perovskite) phases are attracting significant interest because of their unique potential for many applications requiring mixed ionic and electronic conductivity. Here we report a new, previously undiscovered layered perovskite of composition, CexSr2-xMnO4 (x = 0.1, 0.2, and 0.3). Furthermore, we demonstrate that this new system is suitable for solar thermochemical hydrogen production (STCH). Synchrotron radiation X-ray diffraction and transmission electron microscopy are performed to characterize this new system. Density functional theory calculations of phase stability and oxygen vacancy formation energy (1.76, 2.24, and 2.66 eV/O atom, respectively with increasing Ce content) reinforce the potential of this phase for STCH application. Experimental hydrogen production results show that this materials system produces 2-3 times more hydrogen than the benchmark STCH oxide ceria at a reduction temperature of 1400 degrees C and an oxidation temperature of 1000 degrees C.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据