期刊
CORROSION SCIENCE
卷 158, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2019.07.003
关键词
In-situ SEM; Aluminium; High temperature corrosion; Molten salts; Laser cladding; FeCrAl; KCl; HCl
资金
- Engineering and Physical Sciences Research Council [EP/L016362/1]
- Uniper Technologies Limited
This study investigated the effects of HCl and KCl on a laser-clad FeCrAl coating at 450 degrees C in an in-situ ESEM followed by a furnace exposure. In all in-situ TEM cross-sections, three major phases were identified: an iron rich oxide, an iron-chromium mixed oxide and an aluminium enriched layer. HCl allowed chlorine based corrosion to occur which suggests interaction from its gas phase. EDX of the regions around KCl crystals showed a decrease in chromium which is an indication of chlorine selectively removing chromium. Moreover, the mass gain in HCl with KCI was significantly lower than that observed in air with KCl.
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