期刊
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
卷 572, 期 -, 页码 237-249出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.colsurfa.2019.04.018
关键词
TiO2 nanotube arrays; Ag3PO4; Photocatalytic degradation; Antibacterial activity
资金
- Science and Technology Innovation Talents Program of Xinxiang [CXRC17001]
- Major Science and Technology Program for Water Pollution Control and Treatment of China [2015ZX07204-002]
- Natural Science Foundation of Henan Province [162300410212]
- special fund for topnotch talents in Henan Agricultural University [30500600]
- Project Plan of Key Scientific Research in Colleges and Universities of Henan Province [16A150060, 19A610001]
- Department of Chemistry, School of Basic Medical Sciences, Xinxiang Medical University, Xinxiang, Henan China
- Science and Technology Key Projects of Xinxiang City [CXGG17004]
A novel highly ordered TiO2 nanotube arrays (TiO2 NTAs) have been successfully prepared via a simple, costeffective and environmentally friendly corn-silk-templated strategy, and Ag3PO4 nanoparticles were deposited onto the TiO2 surface by a facile in-situ growth method. The crystal structure, morphology and optical properties of the as-prepared samples were characterized via a series of characterized techniques. Systematic studies demonstrated that Ag3PO4/TiO2 heterojunction photocatalyst displayed enhanced photocatalytic activity for rhodamine B (RhB) and ciprofloxacin (CIP) degradation compared to pristine TiO2 NTAs and Ag3PO4. In addition, Ag3PO4/TiO2 heterojunction exhibited significantly superior antibacterial activity than single component. By UV-vis diffuse reflectance (DRS) and photoluminescence (PL) spectra, the Ag3PO4/TiO2 heterojunction showed enhanced adsorption of visible light and reduced recombination of photo-generated electrons (e-) and holes (h(+)). The photocurrent and electrochemical impedance spectroscopy (EIS) demonstrated that Ag3PO4/TiO2 heterojunction possessed a faster photocurrent, lower charge migration resistance compared to pristine TiO2 NTAs and Ag3PO4. The possible enhanced photocatalytic degradation and disinfection mechanism were studied by employing the active species trapping and electron spin resonance (ESR) experiments, indicating that h(+) and superoxide radicals (center dot O-2(-)) played significant roles during the photocatalytic process. This work provided an attractive avenue to design highly ordered TiO2 nanotube arrays based composite photocatalysts from corn silks for pathogenic bacteria and organic pollutants wastewater purification and will be useful for design of other highly ordered nanotube arrays photocatalysts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据