期刊
CHIRALITY
卷 31, 期 8, 页码 561-567出版社
WILEY
DOI: 10.1002/chir.23100
关键词
chiral phosphahelicenes; coordination chemistry; helical chirality; palladium (II) complexes
资金
- Agence Nationale de la Recherche [ANR-15-CE29-0012-01] Funding Source: Medline
- Agence Nationale de la Recherche (ANR) [ANR-15-CE29-0012-01] Funding Source: Medline
- Centre National de la Recherche Scientifique (CNRS). Funding Source: Medline
- Indo-French Centre for the Promotion of Advanced Research [N° 5505-2, 2016] Funding Source: Medline
- Indo-French Center for the Promotion of Advanced Research [5505-2, 2016] Funding Source: Medline
- Agence Nationale de la Recherche (ANR) [ANR-15-CE29-0012] Funding Source: Agence Nationale de la Recherche (ANR)
As a complement to our previous studies on the development of a class of chiral phosphahelicenes, this article discloses the synthesis, spectroscopic, and structural characterizations of a new phosphahelicene transition metal complex. It demonstrates the ability of these hindered chiral ligands to coordinate Pd (II) in trans-complexes Cl2Pd(L*)(2). In the solid state, the complex adopts a C2-symmetric arrangement with two ligands facing each other on the same face of the coordination plane. X-Ray data highlight bending of the Pd (II) unit from the expected planar coordination geometry that might be due to a significant pi-pi stacking effect between the central rings of two helical units.
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