期刊
CHEMPHYSCHEM
卷 20, 期 22, 页码 3030-3036出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201900577
关键词
graphene; electrical conductivity; layered double hydroxide; liquid-phase exfoliation; oxygen evolution reaction
资金
- Deutscher Akademischer Austauschdienst (DAAD)
- Consejo Nacional de Ciencia y Tecnologia (CONACyT)
Earth-abundant transition-metal-based catalysts are attractive for alkaline water electrolysis. However, their catalytic properties are often limited by their poor electrical conductivity. Here, we present a strategy for enhancing the electrical conductivity of NiFe layered double hydroxide (LDH) in order to further improve its properties as an electrocatalyst for the oxygen evolution reaction (OER) in alkaline media. We show that NiFe LDH containing metal tetrasulfonate phthalocyanine in the interlayers between the NiFe oxide galleries can be coupled with graphene during liquid-phase exfoliation by taking advantage of their pi-pi stacking capabilities. A substantial enhancement in the electrocatalytic activity of NiFe LDH with respect to the OER was observed. Moreover, the activity and selectivity of the catalyst materials towards the oxygen reduction reaction were investigated, demonstrating that both the metal hydroxide layer and the interlayer species contribute to the electrocatalytic performance of the composite material.
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