期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 25, 期 45, 页码 10585-10589出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201902788
关键词
C-H activation; glycoconjugation; glycopeptides; manganese; natural products
资金
- DFG (Gottfried-Wilhelm-Leibniz award)
- CSC
Late-stage C-H glycosylations of structurally complex amino acids and peptides were accomplished by means of racemization-free manganese(I)-catalyzed C-H activation. Thus, glycosylative modifications proved to be viable by a linch-pin approach, featuring chemo- and site-selective C-H transformations. The peptide-saccharide conjugation provided modular access to structurally complex glycopeptides, likewise enabling the assembly of fluorescent-labelled glycopeptides.
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