期刊
CHEMISTRY OF MATERIALS
卷 31, 期 15, 页码 5494-5501出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.9b01068
关键词
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资金
- NSERC Discovery Grant [RGPIN-2017-06467]
- Croatian Science Foundation [4744]
- Defense Threat Reduction Agency [HDTRA1-18-1-0003]
- E. W. R. Steacie Memorial Fellowship [SMFSU 507347-17]
Mechanochemistry enables targeted, rapid synthesis of bimetallic metal-organic frameworks (MOFs) with a controlled 1:1 stoichiometric composition of metal nodes. In particular, ball milling enabled the use of specifically synthesized solid coordination complexes of Zn(II), Mg(II), Ni(II), and Co(II) for the assembly of a range of microporous mixed-metal MOF-74 materials composed of pairs of d-block or main group metals in a predetermined 1:1 stoichiometric ratio, including ZnMg-, ZnCo-, ZnCu-, MgZn-, MgCo-, NiZn-, NiMg-, NiCo-, CoZn-, CoMg-, CoCu-, and MgCa-MOF-74. By using specifically prepared precursors in the synthesis of diverse mixed-metal MOF-74 targets, this rational synthesis represents the first entry of mechano-chemistry into the target-oriented synthesis of mixed-metal MOFs.
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