期刊
CHEMICAL ENGINEERING JOURNAL
卷 367, 期 -, 页码 94-101出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.02.142
关键词
Amine-containing polymers; U(VI); Sorption; DFT calculation
资金
- National Natural Science Foundation of China [21707110, 41703118, 41704088, 41502316, 21822602]
- Longshan academic talent research supporting program of SWUST [18LZX 205, 18LZX 206,17LZX528]
Amine containing polymers (ACPs) were synthesized by heating glyoxal and melamine under argon conditions. The batch characterization, including SEM, FTIR, XRD and XPS techniques, indicated that ACPs had various nitrogen-containing functional groups. The batch experiments indicated that ACPs presented the high removal performances (Qmax = 250 mg/g, calculated by Langmuir model), well stability, strong salt tolerance and great regeneration cycle toward U(VI). XPS analysis confirmed the coordination of U(VI) with nitrogen- or oxygen-containing groups via covalent bonding. The theoretical calculations revealed that the binding energies of U-N, U-O and U-C were -27.49, -16.94 and -11.81 kcal/mol, respectively, indicating that U(VI) was tended to combine with nitrogen- containing groups. These observations suggested that ACPs can be regarded as a promising adsorbent for immobilization and pre-concentration of U(VI)-containing wastewater in environmental cleanup.
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