4.7 Article

Improving the performance of the Ba0.5Sr0.5Co0.8Fe0.2O3-δ cathode for Check for proton-conducting SOFCs by microwave sintering

期刊

CERAMICS INTERNATIONAL
卷 45, 期 16, 页码 20994-20998

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2019.06.281

关键词

Cathode; Proton-conducting oxide; Interface; Solid oxide fuel cells

资金

  1. National Natural Science Foundation of China [51602238]
  2. Natural Science Foundation of Shandong Province [ZR2018JL017]
  3. Thousand Talents Plan
  4. World-Class Discipline Program of Shandong Province
  5. Taishan Scholar's Advantageous and Distinctive Discipline Program of Shandong Province
  6. Australian Research Council under the ARC Laureate Fellowship Program [FL170100101]

向作者/读者索取更多资源

In this study, we prepared a Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) cathode layer for proton-conducting solid oxide fuel cells using microwave sintering. Unlike traditional sintering, which is carried out at 1000 degrees C for a few hours, the microwave sintering method allows the BSCF cathode layer to adhere well with the electrolyte layer after sintering at 900 degrees C for 10 min. This strategy helps the cathode layer maintain a microstructure favourable for cathode reactions and mitigate the potential diffusion of elements between it and the BaZr0.1Ce0.7Y0.2O3-delta electrolyte, leading to improved cell resistance. The cell with the BSCF cathode layer sintered by the microwave method has a power output of 0.96 W cm(-2) at 700 degrees C, while the power output for the cell with a conventionally sintered cathode is 0.33 W cm(-2).

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