期刊
APPLIED ORGANOMETALLIC CHEMISTRY
卷 33, 期 8, 页码 -出版社
WILEY
DOI: 10.1002/aoc.5017
关键词
heterogeneous catalysis; layered zirconium carboxyphosphonate; Pd(0)/Pd(II) nanoaggregate
资金
- Science and Engineering Research Board [EMR/2016/002178]
Mixed valent Pd(0)/Pd(II) nano-sized aggregates supported onto a chemically robust layered zirconium carboxyphosphonate framework is prepared and its catalytic activity in Suzuki-Miyaura cross coupling reaction is explored. The exceptionally high catalytic efficacy of the heterogeneous catalyst in Suzuki-Miyaura cross coupling reaction is signified by remarkably short reaction time 2 minutes and high turnover frequency of 1.3 x 10(4) hr(-1). The catalyst can be recycled several times without significant loss of catalytic efficacy, while spectroscopic, structural and microscopic investigations suggest the integrity of the catalyst even after fifth catalytic cycle. The unique ability of the zirconium carboxyphosphonate framework to interact strongly with palladium in dual Pd(0)/Pd(II) oxidation states has been attributed to this remarkable augmentation of catalytic efficacy.
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