期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 40, 页码 14110-14114出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201906913
关键词
alkylation; carbon dioxide; C-H functionalization; phosphine ligands; rhodium
资金
- CNRS, UR1
- China Scholarship Council (CSC) [201706780007]
We report the C-H alkylation of biarylphosphines at the ortho ' position(s) with alkenes by using rhodium(I) catalysis, which provides straightforward access to a large library of multifunctionalized phosphines. Some of these modified ligands outperformed commercially available phosphines in the Pd-catalyzed carboxylation of aryl bromides with carbon dioxide in the presence of a photoredox catalyst.
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