期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 34, 页码 11695-11699出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201905225
关键词
actinides; americium; cyclopentadienyl ligands; organometallic complexes; structure elucidation
资金
- Los Alamos National Laboratory (LANL), Laboratory Directed Research and Development (LDRD) Exploratory Research program [20190091ER]
- J.R. Oppenheimer postdoctoral fellowship (LANL-LDRD)
- U.S. Department of Energy (DOE)
- Office of Science, Basic Energy Sciences (BES) [DE-SC0016568]
- Heavy Element Chemistry Program [DE-SC0004739, DE-AC52-06NA25396]
- Office of Biological and Environmental Research
- DOE Office of Science Graduate Student Research Fellowship (SCGSR) program
- U.S. Department of Energy (DOE) [DE-SC0004739, DE-SC0016568] Funding Source: U.S. Department of Energy (DOE)
We report the small-scale synthesis, isolated yield, single-crystal X-ray structure, H-1 NMR solution spectroscopy /solid-state UV/Vis-nIR spectroscopy, and density functional theory (DFT)/ab initio wave function theory calculations on an Am3+ organometallic complex, [Am(C5Me4H)(3)] (1). This constitutes the first quantitative data on Am-C bonding in a molecular species.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
