期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 32, 页码 10867-10872出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201901818
关键词
anion templation; gigantic cluster; host-guest chemistry; molybdenum blue; polyoxometalates
资金
- EPSRC [EP/J015156/1, EP/L023652/1, EP/I033459/1, EP/K023004/1]
- EC grant MICRE-AGENTS [318671]
- ERC (ERC-ADG) [670467 SMART-POM]
- EPSRC [EP/L023652/1, EP/J015156/1, EP/K023004/1] Funding Source: UKRI
Template-mediated synthesis is a powerful approach to build a variety of functional materials and complex supramolecular systems. However, the systematic study of how templates structurally evolve from basic building blocks, and then affect the templated self-assembly, is critical to understanding and utilizing the underlying mechanism, to work towards designed assembly. Here we describe the templated self-assembly of a series of gigantic Mo Blue (MB) clusters 1-4 using l-ornithine as a structure-directing ligand. We show that by using l-ornithine as a structure director, we can form new template subset of host assemblies. Based on the structural relationship between encapsulated templates of {Mo-8} (1), {Mo-17} (2) and {Mo-36} (4), a pathway of the structural evolution of templates is proposed. This provides insight into how gigantic Mo Blue cluster rings form and could lead to full control over the designed assembly of gigantic Mo-blue rings.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据