期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 59, 期 12, 页码 4624-4633出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201906379
关键词
aromatization; carbon materials; graphene nanoribbons; nanographenes; polycyclic aromatic hydrocarbons
资金
- National Science and Engineering Research Council (NSERC) of Canada
The solution-phase synthesis is one of the most promising strategies for the preparation of well-defined graphene nanoribbons (GNRs) in large scale. To prepare high quality, defect-free GNRs, cycloaromatization reactions need to be very efficient, proceed without side reaction and mild enough to accommodate the presence of various functional groups. In this Minireview, we present the latest synthetic approaches for the synthesis of GNRs and related structures, including alkyne benzannulation, photochemical cyclodehydrohalogenation, Mallory and Pd- and Ni-catalyzed reactions.
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