期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 58, 期 34, 页码 11806-11810出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201907400
关键词
boron; boryl anions; diborane(4) dianions; nucleophilic substitution
资金
- MEXT KAKENHI [17H01191]
Lithium and magnesium salts of tetra(o-tolyl)diborane(4) dianion, having B=B double bond character, were synthesized. It was clarified that the lithium salt of the dianion has a high-lying HOMO and a narrow HOMO-LUMO gap, which were perturbed by dissociation of Li+ cation, as judged by UV/Vis spectroscopy and DFT calculations. The lithium salt of the dianion reacted as two equivalents of a diarylboryl anion with CH2Cl2 or S-8 to give boryl-substituted products.
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