期刊
APPLIED CLAY SCIENCE
卷 132, 期 -, 页码 96-104出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.clay.2016.05.022
关键词
Ti-PILC supported Fe; Catalytic oxidation; Kinetics; Toluene; Mars-Van Krevelen mechanism
资金
- National Natural Science Foundation of China [41302026, 41572032, 41402038]
- Natural Science Foundation of Guangdong Province, China [S2013030014241, 2014A030310141]
- Youth Innovation Promotion Association CAS [2014324]
- CAS/SAFEA International Partnership Program for Creative Research Teams [20140491534]
In this study, TiO2-pillared montmorillonite (Ti-PILC) supported Fe catalysts were synthesized and used for the catalytic oxidation of toluene. The prepared catalysts were characterized by a combination of XRD, N-2 adsorption -desorption isotherms, XPS, H-2-TPR and NH3-TPD. The Fe introduction preserves the mesoporous structure and porosity of Ti-PILC. In the steady-state catalytic test and kinetic analysis, the toluene oxidation over studied catalysts follows the Mars-Van Krevelen mechanism. By the generation of strong acid sites and abundant surface oxygen species, Fe introduction obviously improves the catalytic activity of Ti-PILC for toluene oxidation. But with the increase of Fe content, the activity initially enhances, and then decreases. The effect of Fe species on the promoted toluene oxidation over Ti-PILC was discussed in view of reaction mechanism and above-mentioned variations of physicochemical properties. Furthermore, the Ti-PILC supported Fe catalysts display high stability and superior activity in the presence of water vapor, which present an applied interest. (C) 2016 Elsevier B.V. All rights reserved.
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