MOF-derived C-doped ZnO prepared via a two-step calcination for efficient photocatalysis

ZnO is an important semiconductor that has been widely applied in solar cell, photocatalysis, environmental remediation. Doping and morphology control are important approaches to improve its photocatalytic performance. Herein, a facile two-step calcination method was developed to fabricate carbon(C)-doped cubic ZnO with porous structure from zeolite imidazolate frameworks (ZIF-8). Compared with one-step pyrolysis, the approach of two-step calcination not only retains the cubic morphology with interconnected ZnO nanoparticles and porous structure but also introduces C doping in ZnO lattice effectively. This morphology has advantage in charge transfer, optical absorption and mass transfer during the photoreaction, and C doping results in high charge-separation efficiency. The sample C350-400 (C-doped ZnO, firstly calcined at 350 degrees C for 2 h from ZIF-8, then 400 degrees C for 1 h) shows the maximum photoactivity, which is ca. 3-fold and 4-fold higher than ZnO (C450) in photodegradation and PEC water splitting (under UV-vis irradiation), respectively. It is expected that the preparation of metal oxide from MOF is a very promising way to fabricate highly efficient photocatalyst. (C) 2016 Elsevier B.V. All rights reserved.