4.7 Article

Cross-Coupling Reactions of Alkyl Halides with Aryl Grignard Reagents Using a Tetrachloroferrate with an Innocent Countercation

期刊

ADVANCED SYNTHESIS & CATALYSIS
卷 361, 期 18, 页码 4232-4236

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201900568

关键词

Iron; ferrate salt; cross-coupling reaction; alkyl halide; Grignard reagent

资金

  1. Chugai Award in Synthetic Organic Chemistry, Japan
  2. JSPS KAKENHI [JP17K05805]
  3. Collaborative Research Program of the Institute for Chemical Research, Kyoto University [2018-24]

向作者/读者索取更多资源

Bis(triphenylphosphoranylidene)ammonium tetrachloroferrate, (PPN)[FeCl4] (1), was evaluated as a catalyst for cross-coupling reactions. 1 exhibits high stability toward air and moisture and is an effective catalyst for the reaction of secondary alkyl halides with aryl Grignard reagents. The PPN cation is considered as an innocent counterpart to the iron center. We have developed an easy-to-handle iron catalyst for ligand-free cross-coupling reactions.

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