期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 361, 期 18, 页码 4232-4236出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201900568
关键词
Iron; ferrate salt; cross-coupling reaction; alkyl halide; Grignard reagent
资金
- Chugai Award in Synthetic Organic Chemistry, Japan
- JSPS KAKENHI [JP17K05805]
- Collaborative Research Program of the Institute for Chemical Research, Kyoto University [2018-24]
Bis(triphenylphosphoranylidene)ammonium tetrachloroferrate, (PPN)[FeCl4] (1), was evaluated as a catalyst for cross-coupling reactions. 1 exhibits high stability toward air and moisture and is an effective catalyst for the reaction of secondary alkyl halides with aryl Grignard reagents. The PPN cation is considered as an innocent counterpart to the iron center. We have developed an easy-to-handle iron catalyst for ligand-free cross-coupling reactions.
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