4.8 Article

Cu and Fe oxides dispersed on SBA-15: A Fenton type bimetallic catalyst for N,N-diethyl-p-phenyl diamine degradation

期刊

APPLIED CATALYSIS B-ENVIRONMENTAL
卷 199, 期 -, 页码 323-330

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ELSEVIER
DOI: 10.1016/j.apcatb.2016.06.040

关键词

CuO; Fe2O3; SBA-15; Fenton oxidation; N,N '-diethyl-p-phenyl diamine

资金

  1. Royal Society
  2. Science and Engineering Research Board
  3. CSIR, India [31/6(365)/2012-EMR-I]
  4. STRAIT [CSC0201]
  5. EPSRC [EP/K021796/1, EP/K029525/2]
  6. Engineering and Physical Sciences Research Council [EP/K021796/1, EP/K029525/2] Funding Source: researchfish
  7. EPSRC [EP/K029525/2, EP/K021796/1] Funding Source: UKRI

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A bimetallic oxidation catalyst has been synthesized via wet impregnation of copper and iron over a mesoporous SBA-15 silica support. Physicochemical properties of the resulting material were characterized by XRD, N-2 physisorption, DRUVS, FTIR, Raman, SEM and HRTEM, revealing the structural integrity of the parent SBA-15, and presence of highlydispersed Cu and Fe species present as CuO and Fe2O3. The CuFe/SBA-15 bimetallic catalyst was subsequently utilized for the oxidative degradation of N,N-diethylp-phenyl diamine.(DPD) employing a H2O2 oxidant in aqueous solution. (C) 2016 The Author(s). Published by Elsevier B.V.

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