期刊
MOLECULAR CATALYSIS
卷 468, 期 -, 页码 100-108出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.mcat.2019.02.011
关键词
Carbon nitride; Boron-doped; Lewis acid-base interaction; Oxidative desulfurization
资金
- National Key R&D Program of China [2017YFB0306504]
- National Natural Science Foundation of China [21722604, 21576122, 21808091]
Regulation of electronic properties has been found to be an effective strategy to boost catalytic performance. In this paper, boron doped graphene-analogous carbon nitride (B-C3N4) was prepared and applied in aerobic oxidative desulfurization (ODS) as a metal-free catalyst. Detailed characterizations showed that B atoms have been doped into the framework of carbon nitride, which redistributes the electron structures and appears a stronger Lewis acidity. The B-C3N4 exhibited an impressive sulfur removal to aromatic sulfides, especially to 4,6-dimethyldibenzothiophaene, and the catalytic ability of different sulfides was 4,6-dimethyldibenzothiophene > 4-methyldibenzothiophene > dibenzothiophene. A stronger adsorption progress was constructed between Lewis acid B-C3N4 and Lewis basic aromatic sulfides by the Lewis acid-base interaction, which benefits the next oxidation reaction during the ODS process. After recycling 5 times, the sulfur removal of B-C3N4 could still remain higher than 90%. The current method provides a potential application of B-C3N4 for the removal of 4,6-dimethyldibenzothiophene.
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