4.7 Article

First-Principles Study of FeO2Hx Solid and Melt System at High Pressures: Implications for Ultralow-Velocity Zones

期刊

JOURNAL OF GEOPHYSICAL RESEARCH-SOLID EARTH
卷 124, 期 5, 页码 4566-4575

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AMER GEOPHYSICAL UNION
DOI: 10.1029/2019JB017376

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  1. NSF [EAR-1321956, EAR-1551348, EAR 1764140]

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Pyrite-type FeO2Hx (P phase) has recently been suggested as a possible alternative to explain ultralow-velocity zones due to its low seismic velocity and high density. Here we report the results on the congruent melting temperature and melt properties of P phase at high pressures from first-principles molecular dynamics simulations. The results show that P phase would likely be melted near the core-mantle boundary. Liquid FeO2Hx has smaller density and smaller bulk sound velocity compared to the isochemical P phase. As such, relatively small amounts of liquid FeO2Hx could account for the observed seismic anomaly of ultralow-velocity zones. However, to maintain the liquid FeO2Hx within the ultralow-velocity zones against compaction requires special physical conditions, such as relatively high viscosity of the solid matrix and/or vigorous convection of the overlying mantle. Plain Language Summary Ultralow-velocity zones (ULVZs) are 5-40-km-thick patches lying above Earth's core-mantle boundary. They are characterized with anomalously low seismic velocities compared with the ambient mantle and may contain important clues on the thermochemical evolution of the Earth. A recent experimental study argued that ULVZs may be caused by the accumulation of pyrite-type FeO2Hx (P phase) at the bottom of the mantle. Here for the first time, we systematically study the thermoelastic properties of both FeO2Hx solid and liquid phases. We find that P phase is likely melted near the core-mantle boundary and thus cannot be the source of ULVZs. Furthermore, in order for the molten product of P phase to cause ULVZs, the dense and nearly inviscid melts must be dynamically stable and confined within the ULVZs, which requires that the mantle is highly viscous and/or convects vigorously.

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