期刊
ADVANCED SCIENCE
卷 6, 期 14, 页码 -出版社
WILEY
DOI: 10.1002/advs.201900151
关键词
cathodes; durability; high-energy; MoO3; Zn ion batteries
资金
- National Natural Science Foundation of China [21822509, U1810110, 31530009]
- Fundamental Research Foundation for Universities of Heilongjiang Province [LGYC2018JQ006]
- Science and Technology Planning Project of Guangdong Province [2018A050506028]
- Pearl River Nova Program of Guangzhou [201610010080]
- Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program [2015TQ01C205]
- Province key platforms and projects of Guangdong Universities [2017KQNCX195]
Exploration of high-performance cathode materials for rechargeable aqueous Zn ion batteries (ZIBs) is highly desirable. The potential of molybdenum trioxide (MoO3) in other electrochemical energy storage devices has been revealed but held understudied in ZIBs. Herein, a demonstration of orthorhombic MoO3 as an ultrahigh-capacity cathode material in ZIBs is presented. The energy storage mechanism of the MoO3 nanowires based on Zn2+ intercalation/deintercalation and its electrochemical instability mechanism are particularly investigated and elucidated. The severe capacity decay of the MoO3 nanowires during charging/discharging cycles arises from the dissolution and the structural collapse of MoO3 in aqueous electrolyte. To this end, an effective strategy to stabilize MoO3 nanowires by using a quasi-solid-state poly(vinyl alcohol)(PVA)/ZnCl2 gel electrolyte to replace the aqueous electrolyte is developed. The capacity retention of the assembled ZIBs after 400 charge/discharge cycles at 6.0 A g(-1) is significantly boosted, from 27.1% (in aqueous electrolyte) to 70.4% (in gel electrolyte). More remarkably, the stabilized quasi-solid-state ZIBs achieve an attracting areal capacity of 2.65 mAh cm(-2) and a gravimetric capacity of 241.3 mAh g(-1) at 0.4 A g(-1), outperforming most of recently reported ZIBs.
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