期刊
ENERGY TECHNOLOGY
卷 8, 期 2, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ente.201900245
关键词
electrochemical performance; Karl Fischer titration; lithium-ion batteries; post-drying; water content
资金
- German Federal Ministry for Education and Research (BMBF) [FKZ 03XP0080B]
The post-drying of electrodes and separators for lithium-ion batteries just before cell assembly aims at reducing the water content in the cells below a critical value. This is important as the remaining water can lead to cell degradation and thus cause a safety risk. In addition, it can impede the formation of an effective solid electrolyte interface. Nevertheless, the post-drying of lithium-ion battery electrodes and separators is still poorly investigated. Considering this, three different post-drying procedures are investigated on pouch cells and compared with the non-post-dried state. The remaining water contents are measured via coulometric Karl Fischer Titration and correlated to the resulting electrochemical performance. Surprisingly, the most intensely post-dried cells show the worst electrochemical performance despite reaching the lowest water content. In contrast, the mildest post-dried cells, which show the highest water content, achieve the best electrochemical performance. Further analyses show that extreme post-drying can cause irreparable damages within the electrode structures. Therefore, a good electrochemical performance is not only guaranteed by low remaining water content but also, in particular, by gentle post-drying.
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