期刊
SYMMETRY-BASEL
卷 11, 期 4, 页码 -出版社
MDPI
DOI: 10.3390/sym11040578
关键词
fluorine; amino acids; alkylation; asymmetric synthesis; Ni(II) complexes
资金
- National Natural Science Foundation of China [21761132021]
- IKERBASQUE, Basque Foundation for Science
In this work we report a convenient asymmetric synthesis of Fmoc-(S)-6,6,6-trifluoro-norleucine via alkylation reaction of chiral glycine equivalent. The target amino acid of 99% enantiomeric purity was prepared with 82.4% total yield (three steps).
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