期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 7, 期 12, 页码 10293-10298出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.9b00002
关键词
Base free; Metal free; Dioxygen; Dioxygenation; Aromatic ketone
资金
- Hunan Provincial Natural Science Foundation of China [2019JJ40090, 2019JJ20008]
By employing atmospheric dioxygen as the sole oxidant, an eco-friendly protocol for the clean preparation of various aromatic (cyclic) ketones through phosphinate-promoted oxidation of benzylic C-sp3-H bonds under base-, metal-, additive-, organic-solvent-free conditions has been developed.
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