期刊
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
卷 7, 期 10, 页码 9309-9317出版社
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.9b00357
关键词
Metal phosphides; Nanosheet array; Heterostructure; Hydrogen evolution reaction; Synergistic effect
资金
- National Nature Science Foundation of China [21606111, 21878130]
- Natural Science Foundation of Jiangsu Province [BK20150482]
- China Postdoctoral Science Foundation [2018M642181, 2017T110453]
Design and fabrication of a highly active and earth-abundant hydrogen evolution reaction (HER) electrocatalyst which can work in a wide range of pHs are pivotal for sustainable hydrogen production. In this work, we developed a novel CoP3/CoMoP heterogeneous nanosheet array supported on nickel foam (CoP3/CoMoP/NF HNAs) synthesized from a one-pot phosphidation of CoMoO4 nanosheet arrays. Within this heterojunction, plenty of tiny CoP3 nanoparticles were embedded in the CoMoP nanosheet, forming abundant heterostructure interfaces, which can provide more active sites and improve the electric conduction, consequently improving the catalytic efficiency. The resulting CoP3/CoMoP/NF HNAs exhibited excellent HER activities with a low overpotential of 125 mV at 10 mA cm(-2) and good durability in the acidic media, which ranks in the most-efficient Co-based TMPs electrocatalysts. Furthermore, the CoP3/CoMoP/NF HNAs showed high electrocatalytic HER activities and durability in both neutral and alkaline media. This facile synthesis of a CoP3/CoMoP/NF heterostructure provides a novel way for the fabrication of other heterojunction metal phosphides for hydrogen production from water splitting.
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