期刊
POLYMERS
卷 11, 期 5, 页码 -出版社
MDPI
DOI: 10.3390/polym11050843
关键词
radiation grafting; ion exchange membrane; EVOH; VRFB
资金
- National Natural Science Foundation of China [NSF11875138]
- Key Project of Technological Innovation of Hubei Province [2017AEA107]
A novel amphoteric ion exchange membrane (AIEM) was successfully prepared by one-step radiation grafting of sodium styrene sulfonate (SSS) and dimethylaminoethyl methacrylate (DMAEMA) onto ethylene-vinylalcohol copolymer (EVOH) powder and sequent transferring into film by casting method. Fourier transform infrared spectrometry (FT-IR), thermal gravimetric analyzer (TGA) and elemental analysis testified SSS and DMAEMA were successfully grafted onto EVOH. The ion exchange capacity, water uptake and proton conductivity of the resulting AIEM increased with grafting yield (GY). At the GY of 40.9%, the permeability of vanadium ions of AIEM was 3.98 x 10(-7) cm(2) min(-1), which was better than Nafion117 membrane. Furthermore, the cost of this AIEM is much lower than that of Nafion117 membrane. This work provided a low cost and simple method for fabrication of the ion exchange membrane for vanadium redox flow battery (VRFB). Meanwhile, it also provided a new direction for the application of EVOH.
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