期刊
AIP ADVANCES
卷 9, 期 5, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.5091799
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资金
- South African Research Chairs Initiative (SARChI) of the Department of Science and Technology
- National Research Foundation (NRF) of South Africa [61056]
- Organization for Women in Science for the Developing World (OWSD)
- Swedish International Development Cooperation Agency (Sida)
- NRF through SARChI in Carbon Technology and Materials
- University of Pretoria
Vanadium dioxide (VO2) monoclinic nanosheets were synthesized by a solvothermal method and carbonized iron-polyaniine (C-FP) nanograins were prepared by pyrolysis of iron-polyaniline (PANI) mixture under nitrogen ambient. An asymmetric device (VO2//C-FP) was evaluated with VO2 and C-FP as positive and negative material electrodes in aqueous 6 M KOH electrolyte respectively. The asymmetric supercapacitor (VO2//C-FP) exhibited a 47 mA h g(-1) specific capacity and a specific energy of 30 W h kg(-1) with an associated specific power of 713 W kg(-1) at a gravimetric current of 1 A g(-1) in a potential window of 1.6 V. It also displayed an 89% energy efficiency after 10000 galvanostatic charge-discharge cycles with a large improvement after ageing test at a gravimetric current of 10 A g(-1). (c) 2019 Author(s). All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
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