期刊
MATERIALS
卷 12, 期 9, 页码 -出版社
MDPI
DOI: 10.3390/ma12091510
关键词
industrial solid wastes; petroleum coke desulfurization slag; high belite sulphoaluminate cement; sintering temperature; property
类别
资金
- National Natural Science Foundation of China [51878366, 51578297, 51808310]
- Natural Science Foundation of Shandong Province [ZR2017ZC0737]
In this study, a variety of industrial solid wastes, including petroleum coke desulfurization slag, fly ash and carbide slag with natural resource bauxite, were used as raw materials to prepare high belite suphoaluminate cement, which contains a certain CaSO4 content without adding natural gypsum to the clinker. The sintering temperature, mineral composition, and the physical and mechanical properties of the cement clinkers were investigated. The techniques adopted included a comprehensive thermal analysis (DSC-TG), X-ray diffraction (XRD), X-ray fluorescence (XRF) and scanning electron microscopy (SEM). The results revealed that it is completely feasible to prepare high belite sulphoaluminate cement with the various industrial solid wastes mentioned above and the utilization rate of the solid wastes is up to 80%. The sintering temperature ranges from 1225 degrees C to 1350 degrees C, and the optimal sintering temperature is approximately 1300 degrees C. The clinkers prepared at 1300 degrees C set and harden quickly and have a slightly higher water requirement of normal consistency. The mechanical strength is greatly affected by the CaSO4 and 3CaO3Al(2)O(3)CaSO(4) contents and the most reasonable CaSO4 content is 15%.
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