期刊
ACS CATALYSIS
卷 9, 期 6, 页码 5726-5731出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b01530
关键词
fluoromethylation; borylation; alkene; copper; regioselective
资金
- National Natural Science Foundation of China [21421002, 21332010]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Youth Innovation Promotion Association CAS [2016234]
A copper-catalyzed borylfluoromethylation of alkenes with fluoromethyl iodide and diboron reagents was disclosed. This protocol afforded the previously unknown and synthetically useful borylfluoromethylated alkanes in good yields and excellent regioselectivity. Its synthetic application was illustrated through the derivatization of organoboron products and preparation of monofluorinated ibuprofen.
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