期刊
ACS CATALYSIS
卷 9, 期 6, 页码 5474-5479出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b01338
关键词
C-H functionalization; allylic amidation; dioxazolone; pi-allyl complex; RhCp*; IrCp*; terminal olefins; disubstituted olefins
资金
- National Science Foundation (NSF) under the CCI Center for Selective C-H Functionalization [CHE-1700982]
- NSF [CHE-1531620, CHE-1626172]
An efficient regioselective allylic C-H amidation of mono-, di-, and trisubstituted olefins has been developed. Specifically, the combination of dioxazolone reagents with RhCp* and IrCp* catalysts is reported to promote reactions with complementary regioselectivites to those previously observed in Pd-catalyzed and Ag-promoted Rh-catalyzed reactions. We report that catalyst matching with substrate class is essential for selective reactions. RhCp* complexes are required for high conversion and selectivities with beta-alkylstyrene substrates, and IrCp* complexes are necessary in the context of unactivated terminal olefins.
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