期刊
ACS CATALYSIS
卷 9, 期 5, 页码 4470-4476出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b00209
关键词
visible-light catalysis; asymmetric catalysis; photochemistry; asymmetric cross coupling; fluorine
资金
- NSFC [21432003]
- Fundamental Research Funds for the Central Universities
In the past decades, the Cu-catalyzed asymmetric organic reactions have been well-developed. By contrast, the potential of Cu to serve as a chiral photocatalyst remains underexplored. We here report the visible-light-induced, Cu-catalyzed photoredox enantioselective cyanofluoroalkylation of alkenes. In the reaction, the Cu-based single catalyst played a dual role, as both the photoredox catalyst for the outer-sphere electron transfer and the asymmetric cross-coupling catalyst for enantioselective C-CN bond formation.
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