期刊
ACS CATALYSIS
卷 9, 期 5, 页码 4115-4144出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.9b00656
关键词
photocatalysis; biocatalysis; biotransformation; cascades; cofactor recycling
资金
- European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant [764920]
Light has received increased attention for various chemical reactions but also in combination with biocatalytic reactions. Because currently only a few enzymatic reactions are known, which per se require light, most transformations involving light and a biocatalyst exploit light either for providing the cosubstrate or cofactor in an appropriate redox state for the biotransformation. In selected cases, a promiscuous activity of known enzymes in the presence of light could be induced. In other approaches, light induced chemical reactions have been combined with a biocatalytic step, or light-induced biocatalytic reactions were combined with chemical reactions in a linear cascade. Finally, enzymes with a light switchable moiety have been investigated to turn off/on or tune the actual reaction. This Review gives an overview of the various approaches for using light in biocatalysis.
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