期刊
WATER RESEARCH
卷 154, 期 -, 页码 277-286出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.watres.2019.01.063
关键词
Anaerobic sludge; Electrochemical peroxidation; Electrocoagulation; Electro-Fenton; Wastewater treatment
资金
- Singapore Ministry of Education Academic Research Fund Tier 1 [WBS R302000145112]
In this study, we present a sequential electrochemical process for integral treatment of anaerobic sludge, combining for the first time electrochemical peroxidation (ECP) and electro-Fenton (EF). In the first step, ECP (consisting of H2O2-assisted electrocoagulation with Fe electrodes) was applied as a conditioning and stabilizing method, whose synergistic electrocoagulation/Fenton oxidation effects considerably reduced the COD, TOC and total suspended solids (TSS) by 89.3%, 75.4% and 85.6%, respectively, under optimized conditions (initial pH of 5, [H2O2]/[Fe2+] dose ratio of 5, 15.38 mA cm(-2) and 2 h treatment). Furthermore, total coliforms were completely killed within the first hour of treatment. In the second step, EF was successfully applied to mineralize the remaining organic fraction in the liquid effluent after dewatering, achieving 91.6% and 87.2% of COD and TOC removal, respectively, after 4 h of treatment under optimal conditions (pH 3 and 25 mA cm(-2)), while almost total COD and TOC removal was attained in 8 h. The Fe sludge generated at the end of the ECP treatment was easily dewatered by filtration and 20.9 g of nutrient-rich dry sludge were produced. The overall cost of the ECP-EF treatment was S$ 0.05 L-1 sludge. The combined effects of coagulation and Fenton oxidation during ECP revealed that the treatment efficiency is strongly dependent on the rheological properties of the sludge sample. (C) 2019 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据