期刊
TETRAHEDRON
卷 75, 期 31, 页码 4138-4142出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2019.03.053
关键词
Boranes; Cobalt; Deuteration; Deuterogenolysis; Organoboranates
资金
- National Natural Science Foundation of China [21432011, 21572255, 21732006, 21825109]
Highly efficient hydrogenolysis and deuterogenolysis of diboron compounds have been realized by the use of a cobalt catalyst, affording TON up to 48201. Furthermore, a one-pot two-step procedure comprising sequential deuterogenolysis of diboron and deuteroboration of alkynes under the same cobalt catalyst has been developed for the efficient, atom-economical synthesis of deuterated vinylboronates with high deuterium incorporation and excellent regio- and stereoselectivity. (C) 2019 Elsevier Ltd. All rights reserved.
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