期刊
TALANTA
卷 195, 期 -, 页码 173-180出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.talanta.2018.11.043
关键词
Mesoporous silica; Carboxylic group; Speciation; Chromium; ICP-MS
资金
- National Natural Science Foundation of China [21577057, 91643105, 91543129]
- Natural Science Foundation of Jiangsu Province [BK20171335]
- Analysis & Test Fund of Nanjing University
Carboxyl-group functionalized mesoporous silica (CFMS) prepared by one-pot co-condensation method was employed for the solid phase extraction (SPE) of chromium species for the first time. A new approach of SPE coupled to inductively coupled plasma mass spectrometry (ICP-MS) was thus established for the speciation of chromium in environmental water samples. The influences of pH, volume of sample, extraction time, amount of adsorbent, elution conditions, co-existing ions and adsorption capacity were investigated on adsorption or elution of chromium species. Cr(VI) was not retained on the CFMS material in the pH range of 1.0-9.0, while Cr (III) was quantitatively adsorbed at pH 5.0-9.0. The captured Cr(III) was enriched by using 1.5 mol L-1 HNO3 as elution solvent and detected by ICP-MS. Under the optimized SPE conditions, the maximum adsorption capacity of the CFMS for Cr(III) was 57.67 mg g(-1) and the enrichment factor was 25, with the detection limit (LOD) of 0.02 mu g L-1. The proposed protocol has been successfully applied to chromium speciation in rain, lake and river water samples, which exhibited a prospect in field separation and enrichment of chromium species in environmental waters.
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