期刊
SYNLETT
卷 30, 期 11, 页码 1329-1333出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1611825
关键词
amides; cross-coupling; cyclization; green chemistry; radical reaction; tandem reaction
资金
- National Natural Science Foundation of China [21702083]
- Program for Innovative Research Team (in Science and Technology) in Universities of Yunnan Province
- Yunnan Ten Thousand Talent Program for Young Top-Notch Talents
- Science Foundation Project of Harbin University of Commerce [18XN067]
The first synthesis of 2,3-dihydrotryptamines from acyclic materials and an exo -selective amidoalkylation/cyclization cascade of N -allyl anilines through alpha-C(sp (3) )-H functionalization of simple amides across unactivated alkenes are presented. This reaction proceeds in mixed aqueous media and under metal-free conditions and features a broad substrate scope and a simple operation.
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