期刊
SYNLETT
卷 30, 期 14, 页码 1683-1687出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0037-1611761
关键词
diphenyl diselenide; organoselenium catalysis; green chemistry; benzoin; pollutant destruction; benzoin
资金
- National Key Research and Development Program of China [2018YFD0200100]
- Open Project Program of Jiangsu Key Laboratory of Zoonosis [R1609]
- Opening Foundation of the Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Guizhou University [2016GDGP0104]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
The diphenyl diselenide catalyzed oxidative degradation of benzoin to benzoic acid is reported. As this reaction can convert the malodorous compound into an odorless and innocuous product under mild conditions, it might be useful for pollutant disposal. The reaction does not require a transition-metal catalyst or a chemical oxidant, so that it can be performed at low cost and without generation of wastes. This is believed to be the first example of the use of organoselenium catalysis technology in pollutant destruction, thereby expanding its range of applications.
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