4.7 Article

Novel rhodamine-based colorimetric and fluorescent sensor for the dual-channel detection of Cu2+ and Co2+/trivalent metal ions and its AIRE activities

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.saa.2018.12.017

关键词

Aggregation-induced ratiometric emission; Cell imaging; Coumarin; Fluorescent probe; Metal ions; Rhodamine

资金

  1. National Natural Science Foundation of China [21001040]
  2. Joint Program for Fostering Talents of National Natural Science Foundation of China
  3. Science and Technology Department of Henan Province [182300410183, 162300410011, 162300410236, 152102210343]
  4. Education Department of Henan Province [19A150001, 15B150016, 15HASTIT002]
  5. Foundation of Henan Polytechnic University [T2018-3, J2015-4]
  6. Henan Key Laboratory of Coal Green Conversion (Henan Polytechnic University)
  7. Henan Province [U1304202, U1604124]

向作者/读者索取更多资源

A rhodamine hydrazone 1 bearing coumarin moiety was designed and prepared. Compound 1 exhibited high selectivity toward Co2+ and trivalent metal ions with fluorescence enhancement in CH3OH solution. However, 1 selectively responded to Al3+ in nearly pure H2O media and was further applied to monitor Al3+ in live cells. Moreover, 1 could also act as a colorimetric probe toward Cu2+ in either CH3OH or H2O solution. In addition, sensor 1 displayed aggregation-induced ratiometric emission (AIRE) activities in mixed H2O/CH3OH solution. (C) 2018 Elsevier B.V. All rights reserved.

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