期刊
SMALL
卷 15, 期 18, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.201900348
关键词
2D MOFs; free-standing Ni-Ni3S2@carbon nanoplates; OER
类别
资金
- National Natural Science Foundation of China [51874357, 51872333]
- Natural Science Foundation of Hunan Province, China [2019JJ10006]
- Shenghua Scholar Program of Central South University
- JSPS KAKENNHI [18H03869]
2D metal-organic frameworks (2D MOFs) are promising templates for the fabrication of carbon supported 2D metal/metal sulfide nanocomposites. Herein, controllable synthesis of a newly developed 2D Ni-based MOF nanoplates in well-defined rectangle morphology is first realized via a pyridine-assisted bottom-up solvothermal treatment of NiSO4 and 4,4-bipyridine. The thickness of the MOF nanoplates can be controlled to below 20 nm, while the lateral size can be tuned in a wide range with different amounts of pyridine. Subsequent pyrolysis treatment converts the MOF nanoplates into 2D free-standing nitrogen-doped Ni-Ni3S2@carbon nanoplates. The obtained Ni-Ni3S2 nanoparticles encapsulated in the N-doped carbon matrix exhibits high electrocatalytic activity in oxygen evolution reaction. A low overpotential of 284.7 mV at a current density of 10 mA cm(-2) is achieved in alkaline solution, which is among the best reported performance of substrate-free nickel sulfides based nanomaterials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据